Amazing Spider-Man #344

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A security guard is investigating a noise within a warehouse, and believing it to be a rat he soon leaves. Slightly peeved that he was mistaken for a sewer- dwelling rodent, Spider-Man hops down from his hiding place and resumes taking photos of tankers marked as hazardous material. They contain chemicals vital to process cocaine which are being shipped in large quantities to South America in a perfectly legal transaction. As the authorities are powerless, Spider-Man is making it public so as to bring the organization down. Suddenly there is an explosion and Cardiac begins to take out the workers with an electrified staff. The security guards open fire on Cardiac but his suit is apparently bullet proof. 

1st cameo appearance of Cletus Kasady (becomes Carnage)

1st appearance of Elias Wirtham as Cardiac