Marvel Team-Up (vol 1) #111 featuring Spider-Man and Demon Slayer VF

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In the midst of stopping a crime, Spider-Man meets his Uncle Ben! But he turns out to be a Serpentine in disguise, part of a race of Serpents vowed to take over the Earth. Thus, Spider-Man teams up with the Devil-Slayer, but in the process, is dealt with a deadly Serpent bite that might very well kill him! To be continued in the next issue.